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Visible‐Light‐Mediated Synthesis of Aryl Ketones and Aldehydes from N‐(acyloxy)phthalimides Esters

Year: 2024

Type: article

Abstract: A visible‐light‐mediated decarboxylative oxidation of benzylic redox active esters is described. A diverse array of aromatic ketones or aldehydes could be achieved (15 examples) from secondary or primary aliphatic carboxylic acids. A mechanism involving resonance transformation in the presence of Cs2CO3 is proposed.

Source: Asian Journal of Organic Chemistry

DOI: 10.1002/ajoc.202400008

Authors: Di Ding, Ruiying Wan, Yuchen Qi, Lili Gong, Zixuan Zhang, Haixing Guan, Wei Li, Qingjun Zhu

Institution: Shandong University of Traditional Chinese Medicine

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funder: Shandong University

OpenAlex ID: W4390892664

FWCI:

Cites: 44

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Related to: 10