Work

C(sp 2 )–H selenylation of substituted benzo[4,5]imidazo[2,1- b ]thiazoles using phenyliodine( iii )bis(trifluoroacetate) as a mediator

Year: 2024

Type: article

Abstract: ]thiazole derivatives was devised to synthesize structurally orchestrated selenoethers with good to excellent yields. This PIFA [bis(trifluoroacetoxy)iodobenzene]-mediated protocol operates under mild conditions and offers broad functional group tolerance. In-depth mechanistic investigation supports the involvement of radical pathways. Furthermore, the synthetic utility of this methodology is portrayed through gram-scale synthesis.

Source: RSC Advances

DOI: 10.1039/d4ra00057a

Authors: Prasanjit Ghosh, Gautam Chhetri, Anirban Mandal, Yu Chen, William H. Hersh, Sajal Das

Institutions: North Bengal University, Queens College, CUNY, The Graduate Center, CUNY, City University of New York

Language: English

Topic: Organoselenium and organotellurium chemistry

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,042

Funders: Department of Science and Technology, Ministry of Science and Technology, India, University Grants Commission