Tuning the redox profile of the 6,6′-biazulenic platform through functionalization along its molecular axis
Year: 2024
Type: article
Abstract: Hammett parameters of the substituents over >600 mV range. X-ray crystallographic analysis of the 2,2'-dichloro-substituted derivative revealed unexpectedly short C-Cl bond distances, along with other metric changes, suggesting a non-trivial cycloheptafulvalene-like structural contribution.
Source: Chemical Communications
DOI: 10.1039/d4cc00656a
Institutions: University of Kansas, St. Catherine University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Awards: MRI: Acquisition of a High-Performance Computing Cluster for Science and Engineering Research at the University of Kansas, MRI Consortium: Acquisition of a Single-Crystal X-ray Diffractometer for a Regional PUI Molecular Structure Facility, G2800866775, G3157943389, Design of oligozulene-based organometallics for probing new paradigms in charge delocalization, transport, and storage at the nanoscopic scale, G4676450139, Avance II 500 High Performance Digital NMR Spectrometer System, AVIII HD 400 NMR spectrometer to replace existing DRX 400, MRI: Upgrade of a 500 MHz Nuclear Magnetic Resonance Spectrometer, G6037051216, G6224602641, G64694110, Graduate Research Fellowship Program (GRFP), G7344426795, MRI: Acquisition of a Multinuclear Broadband Cryogenically Cooled Probe for NMR Spectroscopy at KU-Lawrence, G8253886072, G8601798968, G9000150948, Kansas IDeA Network of Biomedical Research Excellence 5
OpenAlex ID: W4394939434