Work

Ni(2,2′:6′,2′′-terpyridine) 2 : a high-spin octahedral formal Ni(0) complex

Year: 2024

Type: article

Abstract: = 2). The crystal structure shows an octahedral geometry, with molecules arranged in independent dimers involving π-stacking between pairs of complexes. Magnetic measurementes and DFT calculations suggest the existence of temperature-dependent intermolecular antiferromagnetic coupling in the solid state.

Source: Dalton Transactions

DOI: 10.1039/d3dt04247b

Authors: Natalia Cabrera-Lobera, Estefanía del Horno, M. Teresa Quirós, Elena Buñuel, Magali Gimeno, William W. Brennessel, Michael L. Neidig, José Luis Priego, Diego J. Cárdenas

Institutions: ORFEO-CINQA Research Network, Universidad Autónoma de Madrid, Universidad de Alcalá, University of Oxford, University of Rochester, Universidad Complutense de Madrid

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funders: Ministerio de Ciencia, Innovación y Universidades, National Institutes of Health, National Institute of General Medical Sciences

Awards: G1839915149, G2898458380, G9000037150

OpenAlex ID: W4396541544

FWCI: 0.157

Cites: 53

Cited by: 2

Related to: 10