Work

Exploring the influence of H-bonding and ligand constraints on thiolate ligated non-heme iron mediated dioxygen activation

Year: 2024

Type: article

Abstract: (5), the latter of which contains a more flexible ligand. These kinetic results afford an experimentally determined reaction coordinate that illustrates the influence of H-bonding and ligand constraints on the kinetic barrier to dioxygen activation an essential step in biosynthetic pathways critical to life.

Source: Chemical Science

DOI: 10.1039/d4sc02787f

Authors: Maike N. Lundahl, Maria B. Greiner, Marc C. Piquette, Paige M. Gannon, Werner Kaminsky, Julie A. Kovacs

Institutions: University of Washington, Tufts University

Language: English

Topic: Metal-Catalyzed Oxygenation Mechanisms

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Institutes of Health, National Institute of General Medical Sciences

Award: Understanding How Thiolates Promote Dioxygen Chemistry