A Network Approach for the Accurate Characterization of Water Lines Observable in Astronomical Masers and Extragalactic Environments
Year: 2024
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide The water molecule, crucial to the chemical composition and dynamics of the universe, is typically identified in its gas phase via radio and submillimeter transitions, with frequencies up to a few THz. To understand the physicochemical behavior of astronomical objects, accurate transition frequencies are required for these lines. From a set of 26 new and 564 previous Lamb dip measurements, utilizing our ultrasensitive laser-based spectrometers in the near-infrared region, ultrahigh-precision spectroscopic networks were set up for H 2 16 O and H 2 18 O, augmented with 40 extremely accurate frequencies taken from the literature. Based on kHz-accuracy paths of these networks, considerably improved line-center frequencies have been obtained for 35 observed or predicted maser lines of H 2 16 O, as well as for 14 transitions of astronomical significance of H 2 18 O. These reference frequencies, attached with 5–25 kHz uncertainties, may help future studies in various fields of astrochemistry and astrophysics, in particular when precise information is demanded about Doppler-velocity components, including the gas flows of galactic cores, the kinematics of planetary nebulae, or the motion in exoplanetary atmospheres.
Source: ACS Earth and Space Chemistry
Institutions: Vrije Universiteit Amsterdam, Eötvös Loránd University
Language: English
Subfield: Spectroscopy
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W4401459094