Work

A semi-mechanistic aging model of Pb added to soil by a modified stable isotope dilution technique

Year: 2024

Type: article

Abstract: The aging of Pb added to soils has not been studied by the isotopic technology because of difficulties in determination of isotopically exchangeable Pb in soil, so that a set of 10 typical agricultural soils in China and a one-year aging experiment with the addition of water-soluble Pb to the soils were carried out. A modified stable isotope dilution technique to determine isotopically exchangeable Pb in soil was developed where 0.2 mM EDTA (ethylenediaminetetraacetic acid) as the extractant. When water-soluble Pb was added to soil, the isotopically exchangeable Pb (E add %, the percentage of isotopically exchangeable Pb to total Pb added to soil) initially decreased rapidly and gradually slowly. A semi-mechanistic aging model of Pb added to soils, including precipitation/nucleation (Y 1 ), micropore diffusion (Y 2 ), and organic matter encapsulation processes (Y 3 ) was developed with the root mean square error 8.3% where Y 1 , Y 2 , and Y 3 accounted for 0.02~26.9%, 1.4~21.8% and 3.8~11.3%, respectively, when the pH 4.0~8.0 and organic matter 2.0~6.0%. Soil pH was a vital factor affecting the aging rate. When the pH increased by 1 unit, the E add value decreased by approximately 9%. The model could be used to scale ecotoxicological data of Pb in soil generated in different aging times.

Source: Scientific Reports

DOI: 10.1038/s41598-024-69375-7

Authors: Xuezhi Ji, Jumei Li, Shuo Sun, Ying Zhong, Yibing Ma