Work

Heat capacity of periodically driven two-level systems

Year: 2024
Type: article
Abstract: We define the heat capacity for steady periodically driven systems and as an example we compute it for dissipative two-level systems where the energy gap is time-modulated. There, as a function of ambient temperature, the Schottky peak remains the dominant feature. Yet, in contrast with equilibrium, the quasistatic thermal response of a nonequilibrium system also reveals kinetic information present in the transition rates; e.g., the heat capacity depends on the time-symmetric reactivities and changes by the presence of a kinetic barrier. It still vanishes though at absolute zero, in accord with an extended Nernst heat postulate, but at a different rate from the equilibrium case. More generally, we discuss the dependence on driving frequency and amplitude.
Language: English
Open Access status: green
OpenAlex ID: W4401515616
FWCI: 0.744
Cites: 21
Cited by: 5
Related to: 10