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Switchable Synthesis of Tritylone Alcohols and 2-Benzoylbenzoate Esters from Spiroindane-1,3-diones

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide A solvent-controlled regioselective rearrangement reaction of spiroindane-1,3-diones with a leaving group has been developed. In acetonitrile solvent, the spiroindane-1,3-diones 3 were rearranged to provide tritylone alcohols, while 2-benzoylbenzoate ester derivatives were obtained if the reactions were performed in alcohols.

Source: The Journal of Organic Chemistry

DOI: 10.1021/acs.joc.4c01296

Authors: Jen-Yu Kuan, Jing-Huei Chen, Jeng-Liang Han

Institution: National Chung Hsing University

Language: English

Topic: Organic Chemistry Synthesis Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500

Funder: National Science and Technology Council