Work

Determining the stopping power of low kinetic energy Ne+ projectiles in self-Assembled monolayers

Year: 2024

Type: article

Abstract: Neutral impact collision ion scattering spectroscopy (NICISS) is used to measure the energy loss in organic self-assembled monolayers (SAMs) on Au using Ne + with low kinetic energies from 3 to 5 keV. With increasing film thickness, the energy loss of the projectiles increases because the projectile experiences more collisions with target atoms. Through comparing Monte-Carlo simulations with the NICISS experiments, it was found that contributions from nuclear stopping for Ne + were significantly larger than for He + mainly due to the stronger contribution of small-angle scattering of Ne + making Ne NICISS unsuitable for depth profiling at energies of 5 keV or lower. The measured Ne + electronic stopping in SAMs is small despite the large atomic number of Ne. Comparing experiments and DFT calculations shows that the latter accurately reproduce stopping powers for Ne + , while SRIM overestimates the stopping power. This contrasts He + ions, where DFT and SRIM align closely with experiments.

Source: Chemical Physics

DOI: 10.1016/j.chemphys.2024.112425

Authors: Ahlam R.M. Alharbi, Pedro L. Grande, Ingo Köper, Anand Kumar, Gunther G. Andersson

Institutions: Flinders University, Flinders Microscopy and Microanalysis, Universidade Federal do Rio Grande do Sul, Commonwealth Scientific and Industrial Research Organisation, CSIRO Environment

Language: English

Topic: Ion-surface interactions and analysis

Subfield: Computational Mechanics

Field: Engineering

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,540

Funders: INESC Microsistemas e Nanotecnologias, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior