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Iodomethylation of S-Silylorganyl Mercaptoazole Derivatives with α-Iodoketones

Year: 2024

Type: article

Abstract: The iodomethylation of 2/3-[dimethyl(phenyl)silylmethylthio]-1,3-benzoimidazoles or -1,2,4-triazole with α-iodoketones of the aliphatic and aromatic series in the absence of basic media and solvents leads to formation of unknown salts based on 2/3-mercaptoazolium cations. Reaction of 2-[dimethyl(phenyl)silylmethylthio]-1,3-benzoxazole with α-iodoketones afforded bis(benzoxazol-2-yl)disulfonium derivatives.

Source: Журнал Общей Химии

DOI: 10.31857/s0044460x24030113

Authors: N. O. Yarosh, L. V. Zhilitskaya, I. A. Dorofeev

Institutions: A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Language: English

Topic: Synthesis and Reactivity of Sulfur-Containing Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4401540236

FWCI:

Cites: 25

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Related to: 10