Dye Induced Luminescence Properties of Gold(I) Complexes with near Unity Quantum Efficiency
Year: 2024
Type: article
Abstract: To study the effect of a dye on the photoluminescence (PL) properties of metal complexes, a series of gold(I) complexes were synthesized, containing a 7‐amino‐4‐methylcoumarin luminophore. The complexes are comprised of a coumarin moiety featuring different ancillary ligands, specifically N‐heterocyclic carbenes, triphenylphosphine, and diphenyl‐2‐pyridylphosphine. The synthesized gold(I) complexes are luminescent both in solution and the solid state at room temperature and 77 K. Complexes of different nuclearity, i.e., mono‐, di‐ and trinuclear compounds were synthesized. A clear trend between the nuclearity and the quantum yields can be seen. The coumarin dye not only improves the PL properties, but also enhances the luminescence of trinuclear clusters, which are otherwise known to be weak emitters in solution. The optical absorption properties were investigated in detail by quantum chemical calculations.
Source: Angewandte Chemie
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,250
Funder: Deutsche Forschungsgemeinschaft
OpenAlex ID: W4401866755