Work

Synthesis and EPR Studies of Zinc and Copper Tris(2‐pyridylmethyl)amines (TPMA) Metal Complexes Containing TEMPO Functionalities

Year: 2024

Type: article

Abstract: A new family of stable radical‐containing polytopic ligands based on tris(2‐pyridylmethyl)amines TPMA architecture and their corresponding metal complexes have been synthesized. These molecular systems offered the possibility to investigate how various spin carriers, such as the metal ion and the organic radical, influence their EPR properties mainly through the empirical ratio of peak heights d1/d. Moreover, it has been possible to analyze how different conformations of TEMPO radical units in the molecular skeleton affect the metallic system.

Source: European Journal of Organic Chemistry

DOI: 10.1002/ejoc.202400384

Authors: Elena Badetti, Vega Lloveras, Melvin Raulin, Francesca A. Scaramuzzo, Jaume Veciana, José Vidal‐Gancedo, Giulia Licini, Cristiano Zonta

Institutions: University of Padua, Ca' Foscari University of Venice, Consejo Superior de Investigaciones Científicas, Instituto de Salud Carlos III, Institut de Ciència de Materials de Barcelona, Sapienza University of Rome

Language: English

Topic: Electron Spin Resonance Studies

Subfield: Biophysics

Field: Biochemistry, Genetics and Molecular Biology

Domain: Life Sciences

Open Access status: hybrid

Estimated APC paid: $4,330

Funders: Fondazione Cassa di Risparmio di Padova e Rovigo, Generalitat de Catalunya, Università degli Studi di Padova, Ministerio de Ciencia e Innovación, Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina

Awards: G1150029139, G3664564641, G5257603219, G5845768719, G6938418927, G7703859073, G7731861875, G7967443488, G8920660035

OpenAlex ID: W4401973635

FWCI:

Cites: 52

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Related to: 10