Year: 2024
Type: article
Abstract: . Recently-developed polarisation-transfer techniques are applied to the 103Rh NMR of the Rh(acac)3 coordination complex in solution. Four-bond 1H-103Rh J-couplings of around 0.39 Hz are exploited to enhance the 103Rh NMR signal and to estimate the 103Rh T1 and T2 relaxation times as a function of field and temperature. The 103Rh longitudinal T1 relaxation in Rh(acac)3 is shown to be dominated by the spin-rotation mechanism, with an additional field-dependent contribution from the 103Rh chemical shift anisotropy.
Source: Magnetic Resonance
Language: English
Subfield: Spectroscopy
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $992
Awards: NMR over nine orders of magnitude in the magnetic field, G2126930746, G253409916, G3447065680, Functionalized Magnetic Resonance Beacons for Enhanced Spectroscopy and Imaging, G4577752882, Underpinning Equipment for Magnetic Resonance Research, A Multidisciplinary Research Platform for Nuclear Spins far from Equilibrium, G6515874725, G6672609852, G7010635361, G80114728
OpenAlex ID: W4402070781