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Cover Feature: Similarities and Differences of Hydridic and Protonic Hydrogen Bonding (ChemPhysChem 17/2024)

Year: 2024

Type: article

Abstract: The Cover Feature shows the hydridic hydrogen bond complex (Cp)(CO)₂RuH⋅⋅⋅ICF₃ (left) and the standard hydrogen bond complex IH⋅⋅⋅S(CH₂)₂ (right). Despite the different directions and natures of charge transfer, various characteristics (stabilization energy, red shift of X−H stretching frequency) of the two complexes are similar. The only difference is the dominant energy term: in the former complex, it is the dispersion term, whereas in the latter, it is the electrostatic term. More information can be found in the Research Article by P. Hobza and co-workers (DOI: 10.1002/cphc.202400403).

Source: ChemPhysChem

DOI: 10.1002/cphc.202481703

Authors: Maximilián Lamanec, Jitka Zienertová, Matej Špeťko, Dana Nachtigallová, Pavel Hobza

Institutions: VSB - Technical University of Ostrava, Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry, Palacký University Olomouc

Language: English

Topic: Crystallography and molecular interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4402127690

FWCI:

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