Year: 2024
Type: article
Abstract: The formation of ML2 homoleptic copper(I) and copper(II) complexes from bidentate chiral ligands with C2 symmetry, comprising three types of substituents (namely benzyl, indanyl and phenyl groups), was investigated. The formation of homochiral or heterochiral complexes can be influenced by the nature of the substituents and the geometry induced by the oxidation state of the metal. All the complexes were isolated and characterized, in particular in the solid state by X‐ray diffraction studies. In solution, cyclic voltammetry was used to study ligand association and discrimination induced by the CuI/CuII transition.
Institutions: Centre National de la Recherche Scientifique, Institut de Physique et Chimie des Matériaux de Strasbourg, Université de Strasbourg, Institut polytechnique de Grenoble, Laboratoire d’Electrochimie et de Physico-chimie des Matériaux et des Interfaces, Université Savoie Mont Blanc, Université Grenoble Alpes
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,860
OpenAlex ID: W4402311490