57Fe nuclear resonance vibrational spectroscopic studies of tetranuclear iron clusters bearing terminal iron( iii )–oxido/hydroxido moieties
Year: 2024
Type: article
Abstract: ] cluster without the change of the terminal Fe(iii) oxidation state and its coordination environment. Therefore, the current study provides a quantitative vibrational analysis of how the remote iron centers within the same iron cluster exert exquisite control of the chemical reactivities and thermodynamic properties of the specific iron site that is responsible for small molecule activation.
Source: Chemical Science
DOI: 10.1039/d4sc03396e
Authors: Jin Xiong, Christopher Reed, Barbara Lavina, Michael Y. Hu, Jiyong Zhao, Esen E. Alp, Theodor Agapie, Yisong Guo
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: diamond
Awards: G102163711, G107546177, G1313983767, G1555131915, G1664757510, G1727175286, Track 4: Advanced CI Coordination Ecosystem: Monitoring and Measurement Services, G2287611682, G262962599, G3075337988, Track 1: ACCESS Resource Allocations Marketplace and Platform Services (RAMPS), ACO: An Open CI Ecosystem to Advance Scientific Discovery (OpenCI), G4969551903, G498139845, Track 3: COre National Ecosystem for CyberinfrasTructure (CONECT), G513797252, G5607048534, G6848031779, G6918803902, Synthetic Models of the Oxygen Evolving Complex of Photosystem II, G7466384876, Track 2: Customized Multi-tier Assistance, Training, and Computational Help (MATCH) for End User ACCESS to CI, Understanding How Nonheme Iron-Dependent Enzymes Assemble Pharmacophores: Studies of Cyclopropane, Aziridine, and Isonitrile Formation, Dissect Mechanism of Iron(II)/2-Oxoglutarate Dependent Enzymes Catalyzed Halogenation in Nucleotide Biosynthesis, G969889393, G993149817
OpenAlex ID: W4402357272