Work

Ruthenium(II)-Catalyzed C–H Allylation of N,N-Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination

Year: 2024

Type: article

Abstract: This report describes a Ru(II)-catalyzed C–H allylation of N,N-dialkylthiobenzamides with allyl methyl carbonate. The reaction is carried out using [RuCl2(p-cymene)]2 in the presence of Cu(OAc)2 and Ag2O. This method represents the first example of a Ru-catalyzed C–H allylation directed by a sulfur-containing group. As a further advantage, the method is performed in sustainable and ecofriendly MeCN as the solvent.

Source: Synlett

DOI: 10.1055/a-2415-3708

Authors: Liang Zhao, Runbao Wang, Kun Jin, Rong Zhang, Yaming Li, Chunying Duan

Institutions: Dalian University of Technology, State Key Laboratory of Fine Chemicals

Language: English

Topic: Catalytic C–H Functionalization Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: National Natural Science Foundation of China, Natural Science Foundation of Liaoning Province, Fundamental Research Funds for the Central Universities