Influence of Mg2+ substitution on structural, electrical polarization, and magnetic properties of Sr-based R-type hexagonal ferrites
Year: 2024
Type: article
Abstract: Substitutional effects of Mg 2 ⁺ proceeding the structural, Fourier-transform infrared spectroscopy, scanning electron microscopy, and vibrating sample magnetometer characteristics of Sr₁₋ₓMgₓMn₂Fe₄O₁₁ R-type hexaferrite were systematically investigated for different concentrations (x = 0, 0.25, 0.75, 1.0). Sol-gel technique was adopted to fabricate the material. X-ray diffraction analysis confirmed samples exhibit a single-phase structure of MgMn₂Fe₄O₁₁. Lattice parameters (a and c) and V (unit cell volume) decreased with increasing Mg concentration. Also, a rise in dislocation density was observed, while crystallite size varied. FTIR spectra further corroborated the single-phase hexagonal structure of the manufactured samples. The electric polarization (P-E) loops demonstrated that saturation and P r remanent polarization increased with Mg substitution, while lossy behavior decreased. Magnetic measurements revealed that substituting Mg 2 ⁺ directed toward an initial escalation in saturation magnetization, retentivity, and coercivity, followed by a subsequent decline. Furthermore, VSM analysis indicated that all samples exhibited a combination of ferrimagnetic and paramagnetic behavior.
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,000
OpenAlex ID: W4402563850