Year: 2024
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide The new alane/bis(phosphine) PAlP pincer-type ligands 2-Me and 2-Et have been prepared by protolysis reactions of N -(diisopropylphoshino)acetamide with Me 3 Al or Et 3 Al in a 2:1 ratio. Upon reaction with a “RhCl” source and pyridine, 2-Me gave rise to a (PAlP)RhMe(py) compound ( 4-Me ), while 2-Et led to the analogous hydride complex (PAlP)RhH(py) ( 4-H ), with a migration of the chloride from Rh to Al. 4-Me and 4-H possess the shortest Rh–Al bonds to date.
Source: Organometallics
Institution: Texas A&M University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W4402635182