Work

Isothermal thermoluminescence dating of speleothem growth – A case study from Bleßberg cave 2, Germany

Year: 2024

Type: article

Abstract: Speleothems are a key archive of past climatic and environmental changes. 230 Th/U dating is the most commonly used method to determine speleothem ages. However, incorporation of non-radiogenic thorium may hamper 230 Th/U dating, and samples older than 600 ka also remain out-of-reach. Calcite exhibits a thermoluminescence (TL) signal at 280 °C with a high characteristic saturation dose, and provides significant potential to date carbonate samples over several million years. Hitherto, the application of TL dating for calcite has mainly been hindered by two factors: 1) a spurious TL signal occurring in the high temperature range, and 2) non-uniform dose rate due to U-series disequilibrium. Here we test an isothermal TL (ITL) dating method on a speleothem sample from Bleßberg cave 2, Germany. We show that the ITL signal measured at 240 °C can completely remove the 280 °C TL peak with a negligible TL contribution from the higher temperature range, thus reducing the influence from the spurious signal. The time-dependent dose rate variation can be simulated using the initial radioactivity of 238 U, 234 U, 230 Th and their decay constants. We use the 230 Th/U dating method to provide precise and accurate radiometric ages documenting that the speleothem grew between 425.5 ± 5.4 and 320.5 ± 9.7 ka. The ITL ages (421 ± 23 to 311 ± 23 ka) of four subsamples from the speleothem are consistent with the 230 Th/U ages at isochronous sampling positions, showing the general reliability of the ITL dating method. ITL dating provides a pathway to construct chronologies for palaeoclimate reconstructions for speleothems beyond the range of the 230 Th/U-method and for samples that are unsuitable for U-series dating methods. • ITL 240 signal is sourced from the trap responsible for the 280 °C TL peak. • ITL 240 SAR D e values have higher precision than MAAD D e values of the 280 °C TL peak. • Dose rate variation with U-series disequilibrium has been simulated. • Simulated ITL ages are consistent with 230 Th/U ages. • High dating limit of ITL enables palaeoclimate reconstruction over millions of years.

Source: Quaternary Geochronology

DOI: 10.1016/j.quageo.2024.101628