Work

Electrolytes from Alkoxyalkyl-substituted Imidazolium ionic liquids. Synthesis, characterization, properties and cell performance in LiFePO4 half-cells

Year: 2024

Type: article

Abstract: • Electrolytes derived from LiTFSI and three related 1-alkoxyalkyl-3-methylimidazolium ionic liquids have shown a good performance in LIBs. • The studied properties of the synthesized electrolytes showed correlation with the nature and length of the alkoxyalkyl chain. • Raman data show that the coordination of lithium ion to the TFSI anion is dependent on the number of oxygen atoms in the substituent at position 1- of the imidazolium ring. Additionally, this feature is related to the ionic conductivity of each electrolyte. • The thermal stabilities of the neat ionic liquids and the cognate electrolytes are high enough for practical applications in LIBs. • LiFePO 4 half-cells containing each of the three electrolytes present good electrochemical performance in terms of capacity and cyclability. Electrolytes based on lithium bis(trifluoromethane)sulfonimide (LiTFSI) salt and alkoxyalkyl-substituted imidazolium ionic liquids (ILs) have been studied. We have synthesized three different 1-alkoxyalkyl-3-methylimidazolium TFSI salts with different chain lengths (from 4 to 10 atoms) and with one to three oxygen atoms at position 1- of the imidazole ring. Both the neat ILs as well as the cognate lithium doped electrolytes have been structurally and physicochemically characterized and electrochemically evaluated. Thermal analyses indicate that the glass transition temperature of the electrolytes is displaced to higher temperatures than those of the corresponding neat ILs, being also higher (more positive) upon increasing the number of oxyethylene units. On the other hand, all 1 M LiTFSI doped synthesized electrolytes are thermally stable up to 300 °C. Raman spectroscopy results indicate that the fraction of TFSI anions coordinated to lithium ion decreases on increasing the number of alkoxy units. This finding implies that there is more “free” lithium ion available to link to the ethereal oxygen of the side chain of the imidazolium ring system. This fact influences the ionic conductivity of the neat ILs and their cognate electrolytes. The electrochemical properties —namely high room temperature conductivities as well as wide electrochemical stability windows— indicate that these materials are promising electrolytes for lithium-ion batteries (LIBs). Lithium half-cells using LiFePO 4 (LFP) olivine have been assembled in order to assess the electrochemical performance by means of both cyclic voltammetry and galvanostatic charge/discharge tests. Overall, we have found that the electrochemical performance of these cells is better than that reported 1 M LiTFSI [Pyr 14 ][TFSI], a common electrolyte in LIBs. The generated half-cell from the 1-alkoxyalkyl-3-methylimidazolium TFSI salts possess a high capacity up to 145 mAh∙ g −1 at a current of 2C. The results reported herein show a striking relationship between structure and properties.

Source: Electrochimica Acta

DOI: 10.1016/j.electacta.2024.145096

Authors: Cristina Santamaría, Enrique Morales, J. Manuel Amarilla, Bernardo Herradón

Institutions: Instituto de Ciencia y Tecnología de Polímeros, Instituto de Ciencia de Materiales de Madrid, Instituto de Química Orgánica General

Language: English

Topic: Ionic liquids properties and applications

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: hybrid

Estimated APC paid: $3,870