Work

Three in One: A Versatile p‐i‐n Heterojunction Diode Based on Quasi‐2D Perovskite as a Solar Cell, Red Light Emitting Device and Weak Light Photodetector

Year: 2024

Type: article

Abstract: Quasi‐two‐dimensional (Q‐2D) Ruddlesden‐Popper (RP) perovskites are rapidly developed for photoelectric device applications due to their unique multiple quantum‐well structures and adjustable photoelectric properties. Here, a three‐in‐one multifunctional photoelectric device that integrates photovoltaic (PV), electroluminescence (EL), and photodetection performance based on Q‐2D perovskite, which has not yet been reported, is explored and realized. As a solar cell (SC) mode under standard air mass 1.5G illumination, the optimal device has a power conversion efficiency (PCE) of 10.36%; as a light emitting diode (LED) mode under forward bias, the optimal device emits red light at 753 nm and achieves an EL external quantum efficiency (EQEEL) of 0.42%; as a photodetector (PD) mode under a pulsed laser (660 nm), the optimal device exhibits superior weak‐light detection, with a linear dynamic range (LDR) improvement as wide as 161.8 dB, a high detectivity (D*) of 7.88 × 1012 Jones, a fast rise/fall time of 19.1/35.2 µs and excellent stability. This work is of great significance to enrich the physical connotation and comprehensively improve the use efficiency of the multifunctional device.

Source: Advanced Optical Materials

DOI: 10.1002/adom.202401665