Oxidation behavior of an ultra-high strength and ductile Ni-enriched complex concentrated alloy
Year: 2024
Type: article
Abstract: Recent research work revealed that Ni 43.9 Co 22.4 Fe 8.8 Al 10.7 Ti 11.7 B 2.5 HEA is one of the ultra-high strength and ductile superlattice alloys. In this work, high-temperature oxidation behavior of the as-cast Ni 43.9 Co 22.4 Fe 8.8 Al 10.7 Ti 11.7 B 2.5 alloy was investigated at 1000 ℃ up to 100 h. The oxidized samples were characterized using X-ray Diffractometer, Energy Dispersive Spectroscopy, and X-ray Photoelectron Spectroscopy. The results revealed that the initial microstructure of the alloy consists of face centered cubic (FCC) and L1 2 structures. High-temperature exposure resulted in the formation of Al 2 O 3 and TiO 2 scales during the initial hours of oxidation, which eventually spall-off after 25 h of exposure allowing further oxidation. The results showed that protective oxide layers such as Al 2 O 3 and TiO 2 were not present after 100 h of exposure. The external layer of the 100 h oxidized sample was composed of Fe, Co, and Ni-rich oxides which are known to have mere effective resistance against oxygen ingression. The alloy which has superior strength and ductility may be used for high temperature applications after attaining the thermally stable fine-grain microstructure by suitable thermomechanical processing / providing oxidation resistance coating / by doping with elements having superior oxidation resistance.
Authors: Lakshay Chauhan, Sudeep Kumar T., Sudeep Kumar T., Arout Chelvane, Shanmugasundaram T., Shanmugasundaram T.
Language: English
Topic: High Entropy Alloys Studies
Subfield: Mechanical Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,500
OpenAlex ID: W4402976495