Work

N‐doped and Bowl‐Shaped Azabenzo[3,4]azulenofluorene: Synthesis and Characterization of Bridged Aza‐Triarylamines

Year: 2024

Type: article

Abstract: Triarylamines are frequently employed as electron donor functional groups in a variety of organic electronic materials. We herein report the synthesis and in-depth characterisation of aza-analogues of fully bridged triarylamines, consisting of 5-, 6- and 7-membered rings. The impact of nitrogen doping and π-extension on the structural, electronic and optical-properties of these contorted heteroaromatic PAHs is thoroughly investigated and paves the way for an improved understanding of the structure-property relationships.

Source: Chemistry - A European Journal

DOI: 10.1002/chem.202403004

Authors: Jan Radolko, Ha Minh Tuan, Ricardo Molenda, Alexander Villinger, Peter Ehlers, Peter Langer

Institution: University of Rostock

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,640

Funders: Deutscher Akademischer Austauschdienst, Bundesministerium für Wirtschaftliche Zusammenarbeit und Entwicklung