Enhanced Strong-Field Ionization and Fragmentation of Methanol Using Noncommensurate Fields
Year: 2024
Type: article
Abstract: Electron-initiated chemistry with chemically relevant electron energies (10-200 eV) is at the heart of several high-energy processes and phenomena. To probe these dissociation and fragmentation reactions with femtosecond resolution requires the use of femtosecond lasers to induce ionization of the polyatomic molecules via electron rescattering. Here, we combine noncommensurate fields with intensity-difference spectra using methanol as a model system. Experimentally, we find orders of magnitude enhancement in several product ions of methanol when comparing coherent vs incoherent combinations of noncommensurate fields. This approach not only mitigates multiphoton ionization and multicycle effects during ionization but also enhances tunnel ionization and electron rescattering energy.
Authors: Eladio Prieto, Rituparna Das, Naga Krishnakanth Katturi, Jacob Stamm, Jesse Sandhu, Sung Kwon, Matthew Minasian, Marcos Dantus
Institution: Michigan State University
Language: English
Subfield: Atomic and Molecular Physics, and Optics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: hybrid
Awards: G5366236523, G7659349743
OpenAlex ID: W4403083927