Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems

Year: 2024

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide We report the synthesis of cationic 2,6-bisiminopyridine organoaluminum complexes, [(BIP)AlR 2 ] +, as stable BAr F 4 – or PF 6 – salts, and their reversible single-electron reduction into well-defined paramagnetic species, [(BIP·)AlR 2 ]. Four redox couples, [(BIP)AlR 2 ] +/0, have been fully characterized through structural, spectroscopic, electrochemical and computational techniques.

Source: Inorganic Chemistry

DOI: 10.1021/acs.inorgchem.4c02664

Authors: Juan Manuel Delgado-Collado, Hellen Videa, Pablo J. Serrano-Laguna, M. Ángeles Fuentes, Eleuterio Álvarez, Antonio Díaz Quintana, Antonio J. Martínez-Martínez, Antonio Rodríguez-Delgado, Juan Cámpora

Institutions: Instituto de Investigaciones Químicas, Universidad de Sevilla, Universidad de Huelva

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500

Funders: Ministerio de Ciencia, Innovación y Universidades, Ministerio de Ciencia e Innovación, Universidad de Huelva, Junta de Andalucía, European Regional Development Fund, Agencia Estatal de Investigación

OpenAlex ID: W4403138762