Palladium-Functionalized Polysiloxane Drop-Casted on Carbon Paper as a Heterogeneous Catalyst for the Suzuki–Miyaura Reaction
Year: 2024
Type: article
Abstract: -cyclometalated complex was grafted to polysiloxanes via azide-alkyne cycloaddition. The obtained polymer-metal complex (Pd-PDMS) acts as a catalyst in the Suzuki-Miyaura reaction. Pd-PDMS was drop-casted onto a carbon fiber support, and the resulting membrane demonstrated catalytic activity in the cross-coupling reaction without yield loss after several catalytic cycles. The catalytic membrane allows for easy catalyst recycling and provides ultra-low palladium levels in Suzuki-Miyaura reaction products.
Source: Polymers
Institution: St Petersburg University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,069
Award: G2708844083
OpenAlex ID: W4403172126