Work

Synthesis and crystal structure of sodium (ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolate] octahydrate

Year: 2024

Type: article

Abstract: The title compound, catena -poly[[triaquasodium]-di-μ-aqua-[triaquasodium]-μ-(ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolato]], [Na 2 (C 10 H 22 O 2 P 2 S 4 )(H 2 O) 8 ] n , crystallizes in the triclinic space group P 1 . The dianionic [CH 3 O(CH 2 ) 3 P(=S)(S—)CH 2 CH 2 P(=S)(S—)(CH 2 ) 3 OCH 3 ] 2− ligand fragments are joined by a dicationic [Na 2 (H 2 O) 8 ] 2+ cluster that includes the oxygen of the methoxypropyl unit of the ligand to form infinite chains.

Source: Acta Crystallographica Section E Crystallographic Communications

DOI: 10.1107/s2056989024009642

Authors: Bryan P. Nell, David R. Tyler, Lev N. Zakharov, Dean H. Johnston

Institutions: Ripon College, University of Oregon, Otterbein University

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $500

Funders: National Science Foundation, Directorate for Mathematical and Physical Sciences