Crystal structure and Hirshfeld surface analysis of (nitrato-κ 2 O , O ′)(1,4,7,10-tetraazacyclododecane-κ 4 N )nickel(II) nitrate
Year: 2024
Type: article
Abstract: ) symmetry. The structure displays inter-molecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site. The 1,4,7,10-tetra-aza-cyclo-dodecane (cyclen) backbone has the [4,8] configuration, with three nitro-gen-bound H atoms directed above the plane of the nitro-gen atoms towards the offset nickel atom with the fourth nitro-gen-bound hydrogen directed below from the plane of the nitro-gen atoms. The nitrate anion O atoms are seen to hydrogen bond to the H atoms bound to the N atoms of the ligand.
Authors: Joseph Reibenspies, Nadia Small, Nattamai Bhuvanesh, Gina Chiarella, Vivian Salazar, Bréayshia Pery, Rukiyah Smith, Deja Toole, Shamika Hewage, Harschica Fernando, Eric Reinheimer
Institutions: Texas A&M University, Prairie View A&M University
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $500
OpenAlex ID: W4403339576