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Continuous processing of JP-10 production: Hydroisomerization of endo-tetrahydrodicyclopentadiene to exo-tetrahydrodicyclopentadiene using a novel bimetal catalyst of Ba/Se supported on TiO2/SO4

Year: 2024
Type: article
Abstract: High-energy-density liquid fuels can be utilized as an energetic supplement to conventional fuels and are essential for volume-limited aerospace vehicles to boost payload and flying range. JP-10 has attracted much attention because of its high density, flash point, high volumetric heat, and low freezing point. Here we report the hydroisomerization of endo -tetrahydrodicyclopentadiene to exo -tetrahydrodicyclopentadiene (the main component of JP-10) was investigated over the TiO 2 /SO 4 supported Ba(10 %)/Se(5–20 %) catalysts. This work aims to examine changes in continuous processing settings to maximize exo -THDCPD production, selectivity, and conversion. It was discovered that the synthesized TiO 2 /SO 4 /Ba(10 %)/Se(5–20 %) heterogeneous catalysts were novel, more effective, affordable, environmentally friendly, and simple to produce. The catalyst’s physicochemical characteristics were examined using FT-IR, BET, XRD, HR-SEM, HR-TEM, TGA and NH 3 -TPD. The produced TiO 2 /SO 4 /Ba(10 %)/Se(5–20 %) nano-catalysts have good catalytic activity and a wide range of active Lewis and Brønsted acid sites. Evaluation of the isomerization of endo -THDCPD to exo -THDCPD was conducted in a high-pressure fixed-bed continuous reactor operating at 200 °C, 20 bar of pressure, and 4.0mol/h of H 2 flow rate . According to the investigations, the synthesized catalyst with a 15 % Se load performs exceptionally well, exhibiting 100 % conversion, 98.5 % selectivity, and 98.5 % yield at an H 2 flow rate of 10 ml/min. The isomerized product is used in Jet Propellant-10, a high-density fuel. Under ideal circumstances, exo -THDCPD with a high degree of purity (>98 wt%) was produced without the need for any sort of separation technique.
DOI: 10.1016/j.jscs.2024.101951
Authors: P. Jayapradha, P. Tamizhdurai, C. Kavitha, V.L. Mangesh, Ashma Abubakker, S. Jayakumar, P. Saravanan, Krishna Kumar Yadav, Maha Awjan Alreshidi, Sultan Alshehery, Haifa A. Alqhtani, May Bin-Jumah
Institutions: University of Madras, Koneru Lakshmaiah Education Foundation, St. Joseph’s College of Engineering, Al-Ayen Iraqi University, University of Ha'il, King Khalid University, Princess Nourah bint Abdulrahman University
Language: English
Open Access status: hybrid
Estimated APC paid: $1,490
OpenAlex ID: W4403351481
FWCI: 0.603
Cites: 57
Cited by: 4
Related to: 10