Year: 2024
Type: article
Abstract: Shape‐persistent conjugated nanobelts (CNBs) are fascinating synthetic targets. However, in most cases these are made in low overall yields by applying strategies of macrocyclization followed by (multiple) ring fusion reactions for nanobelt formation. Here, we describe the high yielding synthesis of enantiopure chiral nanobelts in 84 % yield by applying chirality‐assisted synthesis (CAS). The chiral nanobelts were investigated by UV/Vis and CD spectroscopy. By DFT calculations the aromaticity of these structures is discussed.
Source: Angewandte Chemie
Authors: Yogendra Singh, Moritz P. Schuldt, Frank Rominger, Michael Mastalerz
Institution: Heidelberg University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,250
OpenAlex ID: W4403391827