Work

Supported Nickel Nanoparticles as Catalyst in Direct sp3 C−H Alkylation of 9H‐Fluorene Using Alcohols as Alkylating Agent

Year: 2024

Type: article

Abstract: -mono alkylation of fluorene using alcohols as alkylating agents via borrowing hydrogen strategy. The catalytic protocol displayed versatility with high yields of the desired products using various types of primary alcohols, including aryl/hetero aryl methanols, and aliphatic alcohols as alkylating agents. The catalyst Ni NPs@N-C was synthesized via high-temperature pyrolysis strategy, using ZIF-8 as the sacrificial template. The Ni NPs@N-C catalyst was characterized by XPS, HR-TEM, HAADF-STEM, XRD and ICP-MS. The catalyst is stable even in the air at room temperature, displayed excellent activity and could be recycled 5 times without appreciable loss of its activity.

Source: Chemistry - An Asian Journal

DOI: 10.1002/asia.202400989

Authors: Vageesh M, Harsh Joshi, Anupriya A S, Raju Dey

Institution: National Institute of Technology Calicut

Language: English

Topic: Catalytic C–H Functionalization Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,430

Funders: Department of Science and Technology, Ministry of Science and Technology, India, National Institute of Technology Calicut, Department of Chemistry, University of York, Science and Engineering Research Board