Work

Novel Thiourea Ligands—Synthesis, Characterization and Preliminary Study on Their Coordination Abilities

Year: 2024

Type: article

Abstract: -cresol scaffold, unsymmetrical mono-acylated bis-amines and symmetrical bis-thioureas, are obtained by common experiments. It is observed that the reaction output is strongly dependent on both bis-amine and thiocarbamic chloride substituents. The products are characterized by 1D and 2D NMR spectra in solution and by single crystal XRD. A preliminary study on the coordination abilities of selected products is performed by ITC at around neutral media.

Source: Molecules

DOI: 10.3390/molecules29204906

Authors: Stanislava E. Todorova, Rusi I. Rusew, Zhanina S. Petkova, Boris L. Shivachev, Vanya B. Kurteva

Institutions: Bulgarian Academy of Sciences, Institute of Mineralogy and Crystallography "Acad. Ivan Kostov" Bulgarian Academy of Sciences

Language: English

Topic: Supramolecular Chemistry and Complexes

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $3,069

Funder: European Commission