Work

Thermal Transformations in Copper/Sodium-Organosiloxanes of a Globular Structure

Year: 2024

Type: article

Abstract: The thermal and thermo-oxidative transformations in cage-like metal-organosiloxanes of the general formula [RSiO1.5]12[CuO]4[NaO0.5]4 (R= Ph, Me) were studied. It was established that their decomposition occurs in two stages and includes a number of solid-state reactions, leading to the abstraction of organic groups from the silicon atom, the partial or complete reduction of copper atoms, and the release of metallic and oxide phases.

Source: INEOS OPEN

DOI: 10.32931/io2408a

Authors: M. I. Buzin, I. O. Volkov, E. S. Trankina, A. A. Korlyukov, V. S. Papkov

Institutions: Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds

Language: English

Topic: Silicone and Siloxane Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funder: Ministry of Science and Higher Education of the Russian Federation

Award: G2231888424