Molybdenum‐Catalysed Deoxydehydration: Transforming Linear Aliphatic 1,2‐Diols into Terminal Alkenes
Year: 2024
Type: article
Abstract: Molybdenum catalysts bearing ONO, ON(N)O, ON(O)N and ON(S)O ligands were studied for catalytic deoxydehydration of vicinal diols. The complex bearing N′,N′‐bis(2‐hydroxy‐3,5‐dimethylbenzyl)‐N,N‐dimethylethylenediamine ligand afforded full conversion and up to 97% selectivities towards alkenes, when aliphatic vicinal diols were subjected to the reaction at 5 mol% catalyst loading.
Source: Advanced Synthesis & Catalysis
Authors: Normen Peulecke, Mahsa Sadeghi, Sergey Tin
Institution: Leibniz Institute for Catalysis
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,430
OpenAlex ID: W4403502396