Work

Eco-friendly anaerobic oxidation of aryl diazo esters with heterocyclic N -oxide under ball milling: synthesis of 1,2-dicarbonyl systems

Year: 2024

Type: article

Abstract: Herein we report anaerobic oxidation of metal carbenoids generated from aryl diazo esters under ball milling with heterocyclic N -oxide in the presence of catalytic copper( i ) to afford 1,2-dicarbonyls in excellent yield.

Source: RSC Mechanochemistry

DOI: 10.1039/d4mr00097h

Authors: Souvik Guha, Subhabrata Sen, Ludovic Gremaud

Institutions: HES-SO University of Applied Sciences and Arts Western Switzerland, School of Engineering and Architecture of Fribourg, HES-SO Fribourg

Language: English

Topic: Cyclopropane Reaction Mechanisms

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Haute école Spécialisée de Suisse Occidentale, Staatssekretariat für Bildung, Forschung und Innovation, Zürcher Hochschule für Angewandte Wissenschaften

OpenAlex ID: W4403761183

FWCI: 0.847

Cites: 55

Cited by: 6

Related to: 10