Work

Methacrylate-Containing n-Derivatives of N,N-Diethyl-4-(Phenyldiazenyl)Aniline as Initiators in Two-Photon Polymerization

Year: 2024

Type: article

Abstract: The possibility of using a number of methacrylate-containing N,N-diethyl-4-(phenyldiazenyl)anilines with various para-substituents with respect to the azo group (-H, -Br, -NO2) as photoinitiators of radical polymerization is considered. The electrochemical and photoluminescent properties of these compounds have been studied. In the presence of azo dyes, two-photon photopolymerization of pentaerythritol triacrylate was carried out by focused radiation from a femtosecond laser with a wavelength of 780 nm. Structures with minimum linear element sizes of 94 ± 5 nm were obtained by DLW nanolithography, as well as 3D microstructures of complex architecture.

Source: High Energy Chemistry

DOI: 10.31857/s0023119324030022

Authors: M. V. Arsenyev, E. R. Zhiganshin, D. A. Kolymagin, V. A. Ilyichev, R. S. Kovylin, A. G. Vitukhnovsky, S. A. Chesnokov

Institutions: Russian Academy of Sciences, G.A. Razuvaev Institute of Organometallic Chemistry, Moscow Institute of Physics and Technology, P.N. Lebedev Physical Institute of the Russian Academy of Sciences

Language: English

Topic: Nonlinear Optical Materials Studies

Subfield: Biomedical Engineering

Field: Engineering

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4403764767

FWCI:

Cites: 23

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Related to: 10