Work

Synergistic global and local flexibilities in Zr-based metal–organic frameworks enable sequential sieving of hexane isomers

Year: 2024

Type: article

Abstract: two strategies: incorporating steric hindrance to dampen the global framework dynamics and enhancing the metal node rigidity to limit the local vibrations. These findings not only provide a promising adsorbent for the challenging separation of hexane isomers but also offer rational design principles for harnessing flexibility in MOFs.

Source: Chemical Science

DOI: 10.1039/d4sc05749j

Authors: Rundao Chen, Jiaqi Li, Fang Zheng, Fangru Zhou, Bin Sheng, Baojian Liu, Qiwei Yang, Zhiguo Zhang, Qilong Ren, Zongbi Bao

Institution: Zhejiang University

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Natural Science Foundation of Zhejiang Province

Awards: G3659998680, 双重开放金属位点框架材料设计制备及对氙氪吸附分离研究, G4203287376, G4575960730, G7067876613, G8432251240

OpenAlex ID: W4403844874

FWCI: 1.82

Cites: 47

Cited by: 17

Related to: 10