Work

β-to-β Singly Linked Subphthalocyanine Dimers with Effective π-Conjugation

Year: 2024

Type: article

Abstract: In this work, a series of π-conjugated Subphthalocyanine dimers assembled by simple π-bridges were efficiently synthesized through metal-catalyzed reactions. Despite being singly linked, these readily accessible arrays exhibit excellent π-electron communication, significantly perturbing the orbital distribution of conventional SubPcs and inducing notable alterations in their optical properties. The findings presented here demonstrate the potential of SubPcs for constructing curved porphyrin arrays with well-conjugated skeletons and intriguing functionalities.

Source: Organic Letters

DOI: 10.1021/acs.orglett.4c03407

Authors: Daniel Holgado, Marta Gómez-Gómez, Jorge Labella, Tomás Torres

Institutions: Universidad Autónoma de Madrid, IMDEA Nanoscience

Language: English

Topic: Porphyrin and Phthalocyanine Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,500