Preparation of nanocomposite hydrogel based on Fe3O4-TMSPM/poly(HEMA-PEG6MA-IA) for the removal of methylene blue dye from aqueous solution
Year: 2024
Type: article
Abstract: • Fe 3 O 4 -TMSPM/poly(HEMA-PEG 6 MA-IA) nanocomposite hydrogel was prepared using functionalized Fe 3 O 4 as crosslinker. • The prepared nanocomposite hydrogel was characterized by FT-IR, XRD, TGA, and TEM analysis. • Nanocomposite hydrogel was used for the removal of toxic cationic methylene blue dye. • The maximum Langmuir adsorption capacity of the nanocomposite hydrogel was 270.27 mg/g. • The nanocomposite hydrogel can be reused multiple times. In this work, a new hydrogel poly(2-hydroxyethyl methacrylate-co-polyethylene glycol methacrylate-co-itaconic acid) poly(HEMA-PEG 6 MA-IA) covalently crosslinked with Fe 3 O 4 nanoparticles functionalized with 3-(trimethoxysilyl)propyl methacrylate organosilane (TMSPM) was prepared by free radicals, named Fe 3 O 4 -TMSPM/HG. FTIR-ATR, TGA, XRD, and TEM experiments were utilized to explore the Fe 3 O 4 -TMSPM/HG nanocomposite hydrogel. Swelling studies were also carried out in water, in different pH media, and then used in the adsorption of the cationic dye methylene blue (MB) from aqueous media. The factors controlling the adsorption process such as pH, dose, contact time, initial MB concentration, and temperature were investigated. The maximum MB adsorption capacity (270.27 mg/g) using Fe 3 O 4 -TMSPM/HG was obtained under the best conditions pH 8, dose 0.5 mg/mL, contact time 24 h, and ambient laboratory temperature (≈15 °C). The kinetic and isothermal experiments showed that the adsorption of MB followed the pseudo-second-order and Langmuir models. The effect of temperature on the adsorption capacity is related to the swelling, since the Fe 3 O 4 -TMSPM/HG nanocomposite hydrogel exhibit temperature-responsive. After 5 adsorption–desorption cycles, the adsorption decreased by 19 mg/g compared to the initial adsorption capacity. All the experimental results show that the prepared Fe 3 O 4 -TMSPM/HG nanocomposite hydrogel has the potential to be applied as an adsorbent for MB dye.
Source: Results in Chemistry
Language: English
Subfield: Water Science and Technology
Field: Environmental Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,490
OpenAlex ID: W4404016166