Silylation of Nitrogen-Containing Compounds Using Trimethylsilylimidazole in the Active Medium of Hexamethyldisilazane
Year: 2024
Type: article
Abstract: A new silylating system is suggested based on trimethylsilylimidazole in the active medium of hexamethyldisilazane, which allows for the introduction of trimethylsilyl units both at the OH and NH2 groups. The use of this system ensures the synthesis of trimethylsilyl derivatives of amino alcohols in one stage, and, in the case of aniline and N,N-dimethylhydrazine, significantly reduces the reaction time and increases the product yields.
Source: INEOS OPEN
DOI: 10.32931/io2420a
Institution: MIREA - Russian Technological University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
OpenAlex ID: W4404047686