Work

New Method for the Synthesis of 1,3-Diallyl-1,1,3,3-tetramethyldisiloxane

Year: 2024

Type: article

Abstract: A new method for the synthesis of 1,3-diallyl-1,1,3,3-tetramethyldisiloxane is proposed that includes several steps: the synthesis of dicellosolvoxy(dimethyl)silane by the transesterification reaction followed by obtaining allyl(cellosolvoxy)dimethylsilane from it under the action of the Grignard reagent and its condensation. The resulting product was characterized by 1H, 13C, and 29Si NMR spectroscopy as well as gas-liquid chromatography. The yield of the product was more than 90%, its purity was 99%.

Source: INEOS OPEN

DOI: 10.32931/io2415a

Authors: F. D. Krylov, S. N. Ardabevskaia, K. A. Bezlepkina, S. A. Milenin, A. M. Muzafarov

Institutions: Russian Academy of Sciences, Institute of Synthetic Polymeric Materials

Language: English

Topic: Silicone and Siloxane Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funder: Russian Science Foundation

Award: G3243188942