Work

Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Year: 2024

Type: article

Abstract: a concerted, highly regio- and diastereoselective mechanism. This unique reactivity opens pathways to novel seven-membered phosphorus heterocycles with customizable optical properties and a structurally varied array of ligands for transition metal coordination.

Source: Chemical Science

DOI: 10.1039/d4sc06581f

Authors: Lijun You, Daniel Roth, Lutz Greb

Institution: Heidelberg University

Language: English

Topic: Organophosphorus compounds synthesis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Deutsche Forschungsgemeinschaft, China Scholarship Council