Work

2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4´-bipyridine: Synthesis and Structures

Year: 2024

Type: article

Abstract: Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et2mal2–) and 4,4´-bipyridine (4,4´-bipy) are synthesized: {[Zn(H2O)(4,4´-bipy)(Et2mal)]· 0.5C2H5OH·1.5H2O}n (I) and {[Zn4(H2O)2(4,4´-bipy)3(Et2mal)4]·6H2O}n (II). According to the XRD data (CIF files CCDC nos. 2323336 (I) and 2323337 (II)), both compounds are 2D polymers with the sql and bey topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions.

Source: Координационная химия

DOI: 10.31857/s0132344x24080027

Authors: A. S. Chistyakov, E. N. Zorina-Tikhonova, A. V. Vologzhanina, M. A. Kiskin, I. L. Eremenko

Institutions: Russian Academy of Sciences, NS Kurnakova Institute of General and Inorganic Chemistry, A. N. Nesmeyanov Institute of Organoelement Compounds

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4404143435

FWCI:

Cites: 42

Cited by:

Related to: 10