Year: 2024
Type: article
Abstract: Vanadium tris-trifluoroacetylacetonate and tris-pivaloyltrifluoroacetonate were obtained by electrochemical synthesis. Based on the analysis of the spectral characteristics in the IR range of the synthesized chelates, it was established that during electrolysis a quasi-aromatic metallocycle was formed that is the basic structural element of the complexes. The peripheral groups of ligands (tert-butyl and trifluoromethyl) remained unchanged when exposed to electric current.
Authors: N. N. Kostyuk, T. A. Dick, A. R. Tsyhanau
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W4404146404
