Surfactant-assisted phase selective sonochemical synthesis of sodium yttrium fluoride nanoparticles
Year: 2025
Type: article
Abstract: The potential of rare earth-doped sodium yttrium fluoride (NaYF4) as upconverting nanoparticles extends to various applications, from electronics to biology. The hexagonal (β) phase of NaYF4 nanoparticles is known to exhibit a photoluminescence quantum yield higher than the cubic (α) phase. The typical synthetic methods for β-NaYF4 present limitations, such as low colloidal stability in aqueous medium and the need for ligand exchange. Herein, we employed high-throughput robotics, automated sonication, and high-throughput X-ray diffraction (HT-XRD) to synthesize and characterize hundreds of samples under various conditions and obtain NaYF4 nanoparticles dispersible in an aqueous medium. We characterized the samples through XRD for phase determination, SEM and TEM for morphology assessment, UV-Vis spectroscopy and zeta potential for colloidal stability evaluation, and photoluminescence spectroscopy and time-resolved photoluminescence spectroscopy to investigate their upconverting properties. We found that only sodium dodecyl sulfate (SDS) promotes β-NaYF4 formation. The order of addition is also important: adding SDS before the precursor salts leads to pure β-NaYF4 formation. Our proposed mechanism for β-NaYF4 formation involves the initial formation of smaller α-NaYF4 crystals in the presence of SDS, which were more easily converted to β-NaYF4 during sonication compared to the larger α-NaYF4 crystals formed in the absence of SDS.
Source: Ultrasonics Sonochemistry
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,710
Funders: National Science Foundation, U.S. Department of Energy, University of Washington, Office of Science, Clean Energy Institute, Materials Research Science and Engineering Center, Harvard University, National Nanotechnology Coordinating Office, Molecular Engineering and Sciences Institute, University of Washington, Molecular Engineering Materials Center, University of Washington, Chemical Engineering Department, Worcester Polytechnic Institute, Department of Chemical Engineering, Universiti Teknologi Petronas, Basic Energy Sciences, Division of Materials Sciences and Engineering
OpenAlex ID: W4407727624