Work

Lewis Acid‐Catalyzed Isomerization of Donor‐Acceptor Cyclobutanes in the Presence of Thiourea: A New Efficient Route to 2‐ Arylallylmalonates

Year: 2024

Type: article

Abstract: A straightforward access to various substituted 2‐arylallylmalonates from readily available donor‐Acceptor (D‐A) cyclobutanes catalyzed by Al(OTf) 3 in the presence of thiourea is reported. This is a new and convenient approach for isomerization of donor‐acceptor cyclobutanes into 2‐arylallylmalonates.

Source: ChemistrySelect

DOI: 10.1002/slct.202404202

Authors: Ruixin Zhao, Yanqing Zhang, Jintao Zhang, Zuliang Chen

Institutions: Yichun University, State Intellectual Property Office

Language: English

Topic: Organic and Inorganic Chemical Reactions

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funder: National Natural Science Foundation of China

Award: 基于D-A环丁烷的环加成反应研究