Get started
Work

Electrochemical Synthesis of Alkenylsulfonates from Alkynes, NaHSO3 and Alcohols

Year: 2024
Type: article
Abstract: Comprehensive Summary Alkenylsulfonates are commonly encountered in medicinal chemistry, polymer chemistry, and organic synthesis. In this research, an electrochemical reaction involving alkynes, NaHSO3, and alcohols has been developed. This method yields functionalized alkenylsulfonates in good yields with broad functional group tolerance. Mechanism studies indicate that anodic oxidation of inorganic sulfite, radical insertion process, and HAT process are involved in this transformation.
DOI: 10.1002/cjoc.202400962
Authors: Xiaoman Wang, Qianqian Chen, Jinhang Zhou, Yi Hu, Shengqing Ye, Jie Wu
Institutions: Nanjing Tech University, State Key Laboratory of Materials-Oriented Chemical Engineering, Taizhou University, Taizhou University, Chinese Academy of Sciences, Shanghai Institute of Organic Chemistry, State Key Laboratory of Organometallic Chemistry, Henan Normal University
Language: English
Field: Chemistry
Open Access status: bronze
OpenAlex ID: W4404194852
FWCI: 1.67
Cites: 46
Cited by: 12
Related to: 10