Work

Enhanced solid-state reaction synthesis of CdO, SnO, and CdO0·2/SnO0.2 hetero-junction electrode for high-performance energy storage

Year: 2024

Type: article

Abstract: This study unveils a superior method for energy storage synthesis, employing CdO, SnO, and CdO 0·2 /SnO 0.2 hetero-junction electrodes through enhanced solid-state reaction. The CdO and SnO electrodes with a specific capacitance of 266.66, 191.66, 166.66 F/g and 138.88, 122.22, and 115.07 F/g. The CdO 0·2 /SnO 0.2 hetero-junction nanoparticles with a specific capacitance of 370.37, 222.22, 158.73 F/g. The charge storage capacity of CdO 0·2 /SnO 0.2 hetero-junction nanoparticle electrodes is outstanding, making them highly beneficial for energy storage and supercapacitor applications. The XRD patterns obtained from the synthesized CdO 0·2 /SnO 0.2 hetero-junction nanoparticles exhibit distinct diffraction peaks, showing a cubic crystal structure. These diffraction peaks, at 2θ values of 27.111°, 34.189°, 38.682°, 52.635°, 55.793 o , 62.779 o , 66.676 o , and 79.496° can be attributed to the (111), (200), (211), (212), (220), (300), (22), and (311) diffraction planes of CdO 0·2 /SnO 0.2 hetero-junction nanoparticles. The observation of a grain-like shape in the CdO 0·2 /SnO 0.2 hetero-junction nanoparticles structure is attributed to CdO, which serves as a confirmation of the formation of a hetero-junction. The energy bandgap of CdO, SnO, and CdO 0·2 /SnO 0.2 hetero-junction nanoparticles material are 2.50, 3.50, and 3.35 eV respectively. • The CdO electrode with a specific capacitance of 266.66, 191.66, 166.66 F/g. • The SnO electrode with a specific capacitance of 138.88, 122.22, and 115.07 F/g. • The CdO 0.2 /SnO 0.2 hetero-junction nanoparticles with a specific capacitance of 370.37, 222.22, 158.73 F/g. • The energy bandgap of CdO 0.2 /SnO 0.2 hetero-junction nanoparticles material is 3.35 eV.

Source: Chemistry of Inorganic Materials

DOI: 10.1016/j.cinorg.2024.100079